trans-Carbonyl­chloridobis(tri-p-tolyl­phosphine)rhodium(I) acetone solvate

نویسندگان

  • Fabio Lorenzini
  • Brian O. Patrick
  • Brian R. James
چکیده

The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d(6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris-(hydroxy-meth-yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo-octa-diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol-ecules and the acetone mol-ecules are linked into a chain along the a axis by inter-molecular C-H⋯Cl and C-H⋯O hydrogen bonds.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008